Observatorio de I+D+i UPM

Memorias de investigación
Communications at congresses:
Combined grazing incidence RBS and TEM analysis of luminescence nano-SiGe/SiO2 multilayers
Year:2007
Research Areas
  • Electronics engineering
Information
Abstract
Si, SiGe and Ge nanoparticles embedded in an oxide matrix are highly interesting for applications in luminescent devices compatible with CMOS technology. A promising method for the production of SiGe nanoparticles is the deposition of discontinuous layers of SiGe sandwiched by SiO2 using a conventional hot tube Low Pressure Chemical Vapor Deposition reactor. However, the deposited layers have to be subjected to a heat treatment to show the desired luminescent emission. These annealing processes may lead to unwanted composition changes and diffusion. For the present study multilayer structures with five periods of amorphous SiGe nanoparticles/SiO2 and a top SiO2 capping layer with different thickness were deposited in order to increase the area density of SiGe nanoparticles. The use of grazing incidence RBS was, due to the extremely small nominal thickness of the SiGe-layers (less than a monolayer) and SiO2 interlayers, the only possibility to investigate the details of composition changes and diffusion processes occurring in these multilayer systems. The application of a model for the RBS analysis, recently developed by the authors, allowed the determination of the average size and area density of the embedded nanoparticles. Transmission Electron Microscopy (TEM) was used to obtain complementary information on the size and crystallinity of the nanoparticles. The RBS study revealed that annealing at 900ºC for 60 seconds causes a strong degradation of multilayer structures with thin SiO2 interlayers due to Ge diffusion. In samples with thicker interlayers for the same annealing conditions the degradation is limited or absent. High Resolution TEM micrographs of the latter samples showed that the annealing leads to the crystallization of the nanoparticles but leaves their area density or size unaltered. These results enabled to determine the combination of SiGe- and SiO2-layer thickness for which the luminescence yield is maximized.
International
Si
Congress
18th International Conference on Ion Beam Analysis
960
Place
Hyderabad, India
Reviewers
Si
ISBN/ISSN
Start Date
23/09/2007
End Date
28/09/2007
From page
To page
Participants
  • Participante: A Kling
  • Participante: C. Ballesteros (Universidad Carlos III de Madrid)
  • Autor: Andres Rodriguez Dominguez (UPM)
  • Autor: Jesus Sangrador Garcia (UPM)
  • Participante: M.I. Ortiz
  • Autor: Tomas Rodriguez Rodriguez (UPM)
Research Group, Departaments and Institutes related
  • Creador: Departamento: Tecnología Electrónica
S2i 2020 Observatorio de investigación @ UPM con la colaboración del Consejo Social UPM
Cofinanciación del MINECO en el marco del Programa INNCIDE 2011 (OTR-2011-0236)
Cofinanciación del MINECO en el marco del Programa INNPACTO (IPT-020000-2010-22)