Observatorio de I+D+i UPM

Memorias de investigación
Research Publications in journals:
Analysis of the intermediate-band absorption properties of type-II GaSb/GaAs quantum-dot photovoltaics
Year:2017
Research Areas
  • Solar energy,
  • Semiconductors,
  • Phisics,
  • Quantum points,
  • Solar cells
Information
Abstract
Quantum-dot (QD) intermediate-band (IB) materials are regarded as promising candidates for high-efficiency photovoltaics. The sequential two-step two-photon absorption processes that take place in these materials have been proposed to develop high-efficiency solar cells and infrared (IR) photodetectors. In this work, we experimentally and theoretically study the interrelation of the absorptivity with transitions of carriers to and from the IB in type-II GaSb/GaAs QD devices. Our devices exhibit three optical band gaps with: EL = 0.49 eV, EH = 1.02 eV, and EG = 1.52 eV, with the IB located 0.49 eV above the valence band. These values are well supported by semiempirical calculations of the QDs electronic structure. Through intensity-dependent two-photon photocurrent experiments, we are able to vary the filling state of the IB, thus modifying the absorptivity of the transitions to and from this band. By filling the IB with holes via E = 1.32 eV or E = 1.93 eV monochromatic illumination, we demonstrate an increase in the EL-related absorptivity of more than two orders of magnitude and a decrease in the EH-related absorptivity of one order of magnitude. The antisymmetrical evolution of those absorptivities is quantitatively explained by a photoinduced shift of the quasi-Fermi level of the IB. Furthermore, we report the observation of a two-photon photovoltage, i.e., the contribution of subband gap two-photon absorption to increase the open-circuit voltage of solar cells. We find that the generation of the two-photon photovoltage is related, in general, to the production of a two-photon photocurrent. However, while photons with energy close to EL participate in the production of the two-photon photocurrent, they are not effective in the production of a two-photon photovoltage.We also report the responsivity of GaSb/GaAs QD devices performing as optically triggered photodetectors. These devices exhibit an amplification factor of almost 400 in the IR spectral region. This high value is achieved by minimizing?via doping?the absorptivity in the IR range of the QDs under equilibrium conditions.
International
Si
JCR
Si
Title
Physical Review B
ISBN
2469-9950
Impact factor JCR
3,836
Impact info
Volume
96
10.1103/PhysRevB.96.125422
Journal number
12
From page
125422
To page
125435
Month
SEPTIEMBRE
Ranking
Participants
  • Autor: Iñigo Ramiro Gonzalez (UPM)
  • Autor: Juan Villa Morales (UPM)
  • Autor: Cesar Tablero Crespo (UPM)
  • Autor: Elisa Antolin Fernandez (UPM)
  • Autor: Antonio Luque Lopez (UPM)
  • Autor: Antonio Marti Vega (UPM)
  • Autor: J. Hwang
  • Autor: J. Phillips
  • Autor: A. J. Martin
  • Autor: J. Millunchick
Research Group, Departaments and Institutes related
  • Creador: Centro o Instituto I+D+i: Instituto de Energía Solar
  • Departamento: Electrónica Física, Ingeniería Eléctrica y Física Aplicada
S2i 2020 Observatorio de investigación @ UPM con la colaboración del Consejo Social UPM
Cofinanciación del MINECO en el marco del Programa INNCIDE 2011 (OTR-2011-0236)
Cofinanciación del MINECO en el marco del Programa INNPACTO (IPT-020000-2010-22)