Memorias de investigación
Communications at congresses:
Survival probability distributions of microcanonical reactant ensembles in X-CN isomerization reactions
Year:2014

Research Areas
  • Physics chemical and mathematical

Information
Abstract
The classical Hamiltonian dynamics of X-CN three atomic systems have been thoroughly investigated in the past showing an intricate mixture of chaotic and regular phase space structures. The motion in the irregular component is dominated by the stickiness of trajectories close to the boundary circles separating regular from irregular regions. This stickiness significantly affects statistical quantities like Poincaré recurrences and isomerization reaction rates which exhibits algebraic behaviors. In this work, finitetime numerical calculations of X-CN <-> CN-X isomerization reaction rates are carried out in order to assess possible universal non integer microcanonical reaction orders from the reactant decay laws.
International
Si
Congress
The 10th AIMS Conference on Dynamical Systems, Differential Equations and Applications [http://www.aimsciences.org/conferences/2014/]
960
Place
Madrid
Reviewers
Si
ISBN/ISSN
0000-0000
Start Date
07/07/2014
End Date
11/07/2014
From page
437
To page
437
The 10th AIMS Conference on Dynamical Systems Differential Equations and Applications - ABSTRACTS [http://www.aimsciences.org/conferences/2014/abstracts-book-finalized-2014-06-10.pdf]
Participants
  • Autor: Pablo García Müller Ciemat
  • Autor: Rosa Maria Benito Zafrilla UPM
  • Autor: Florentino Borondo Universidad Autónoma de Madrid

Research Group, Departaments and Institutes related
  • Creador: Grupo de Investigación: Grupo de Sistemas Complejos
  • Departamento: Ingeniería Agroforestal