Artículos en revistas:
Meso-scale characterization of lithium distribution in lithium-ion batteries using ion beam analysis techniques
Meso-scale characterization of lithium distribution in lithium-ion batteries using ion beam analysis techniques
Año:2015
Áreas de investigación
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Ingenierías
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Descripción
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| The performance of a Li-ion battery (LIB) is mainly governed by the diffusion capabilities of lithium in the electrodes. Thus, for LIB improvement it is essential to characterize the lithium distribution. Most of the traditionally used techniques for lithium characterization give information about the local scale or in the macroscopic scale. However, the lithium behavior at the local scale is not mirrored at the macroscopic scale. Therefore, the lithium characterization in the mesoscopic scale would be of help to understand and to connect the mechanisms taking place in the two spatial scales. In this paper, we show a general description of the capabilities and limitations of ion beam analysis techniques to study the distributions of lithium and other elements present in the electrodes in the mesoscopic scale. The potential of the 7Li(p,a0)4He nuclear reaction to non-invasively examine the lithium distribution as a function of depth is illustrated. The lithium spatial distribution is characterized using particle induced g-ray (m-PIGE) spectroscopy. This technique allows estimating the density of the active particles in the electrode effectively contributing to the Li intercalation and/or de-intercalation. The advantages of the use of ion beam analysis techniques in comparison to more traditional techniques for electrode characterization are discussed. | |
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Internacional
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JCR del ISI
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Título de la revista
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JOURNAL OF POWER SOURCES |
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ISSN
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0378-7753 |
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Factor de impacto JCR
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5,211 |
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Información de impacto
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Volumen
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299 |
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DOI
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Número de revista
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Desde la página
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587 |
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Hasta la página
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595 |
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Mes
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Ranking
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Participantes
- Autor: Raquel Gonzalez Arrabal (UPM)
- Autor: Miguel Panizo Laiz (UPM)
- Autor: K. Fujita (The Graduate School for the Creation of New Photonics Industries)
- Autor: K. Mima (The Graduate School for the Creation of New Photonics Industries)
- Autor: A. Yamazaki (University of Tsukuba)
- Autor: T. Kamiya (Takasaki Advanced Radiation Research Institute, Japan Atomic Energy Agency)
- Autor: Y. Orikasa (Graduate School of Human and Environmental Studies, Kyoto University)
- Autor: Y. Uchimoto (Graduate School of Human and Environmental Studies, Kyoto University)
- Autor: H. Sawada (Toyota Central R)
- Autor: C. Okuda (Toyota Central R)
- Autor: Y. Kato (The Graduate School for the Creation of New Photonics Industries)
- Autor: Jose Manuel Perlado Martin (UPM)
Grupos de investigación, Departamentos, Centros e Institutos de I+D+i relacionados
- Creador: Grupo de Investigación: Fusión Nuclear Inercial y Tecnología de fusión
- Centro o Instituto I+D+i: Instituto de Fusión Nuclear
S2i 2023 Observatorio de investigación @ UPM con la colaboración del Consejo Social UPM
Cofinanciación del MINECO en el marco del Programa INNPACTO (IPT-020000-2010-22)