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Descripción
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| Films of polymer blends are used in technological applications such as coatings or structured functional layers. The evolution of those films is involved by the coupling of phase separation within the film and surface deformations. We developed a model for films of binary mixtures [1], such as polymer blends, with free evolving surfaces. The model is based on model-H describing the coupled transport of concentration and momentum fields supplemented by boundary conditions at the substrate and free surface. We use the model to analyze the stability of vertically stratified base states of free surface films and the influence of composition in the shape of the films. For purely diffusive transport, an increase in film thickness either exponentially decreases the lateral instability or entirely stabilizes the film. The inclusion of convective transport leads to further destabilization as compared to the purely diffusive case [2]. In addition, we discuss the role of composition for off-critical mixtures on surface deflections. \\[4pt] [1] U. Thiele, S. Madruga, and L. Frastia. Phys. of Fluids. 19, 122106, (2007).\\[0pt] [2] S. Madruga and U. Thiele. Phys. of Fluids. 21, 062104, (2009). | |
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Internacional
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Si |
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Nombre congreso
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The 63rd Annual Meeting of the American Physical Society¿s Division of Fluid Dynamics |
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Tipo de participación
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960 |
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Lugar del congreso
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Long Beach, USA |
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Revisores
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Si |
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ISBN o ISSN
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0003-0503 |
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DOI
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Fecha inicio congreso
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21/11/2010 |
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Fecha fin congreso
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23/11/2010 |
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Desde la página
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203 |
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Hasta la página
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203 |
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Título de las actas
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Interplay between phase separation and surface deformations in thin films |